15 P 30.974

Phosphorus

nonmetal · Group 15 · Period 3

Atomic properties

Atomic number
15
Z
Atomic weight
30.974[1]
g/mol
Density
1.823 g/cm³
at STP
Melting point
44.15 °C
at 1 atm
Boiling point
280.5 °C
at 1 atm
Crystal structure
triclinic
Electron config.
[Ne] 3s² 3p³
Oxidation states
-3, +3, +5
most common

Market data

No tradeable futures market for P on Yahoo / Stooq. Live market data is not available; pricing in this page is based on contract reference figures from the source documents.

Raw material sources & pricing

Raw Material FormGrade/QualityPrice Paid by ProcessorsMajor SourcesNotes
Sedimentary Phosphate Rock28-36% P₂O₅$75-99/MTMorocco, USA, JordanMost common type, easier to process
Igneous Phosphate Rock35-40% P₂O₅$85-110/MTRussia, South Africa, BrazilHigher grade, harder to process
Beneficiated Rock30-33% P₂O₅$80-95/MTChina, VietnamUpgraded low-grade ore
High-Grade Rock>33% P₂O₅$95-120/MTMorocco, RussiaPremium quality for phosphoric acid
Phosphate Rock - Primary Raw Material

Current Market Price: $75-99/MT FOB (varies by location and quality) Major Global Reserves: Morocco & Western Sahara: 50 billion MT (70% of world reserves) China: 3.2 billion MT - World's largest producer Egypt: 2.8 billion MT Algeria: 2.2 billion MT Syria: 1.8 billion MT 2025 Production Leaders: China: 90 million MT (47% of global production) Morocco: 35 million MT United States: 22 million MT Russia: 13 million MT Raw Material Form Grade/Quality Price Paid by Processors Major Sources Notes Sedimentary Phosphate Rock 28-36% P₂O₅ $75-99/MT Morocco, USA, Jordan Most common type, easier to process Igneous Phosphate Rock 35-40% P₂O₅ $85-110/MT Russia, South Africa, Brazil Higher grade, harder to process Beneficiated Rock 30-33% P₂O₅ $80-95/MT China, Vietnam Upgraded low-grade ore High-Grade R

⚠️ Seawater Phosphorus Extraction

Commercial Viability: NOT ECONOMICALLY VIABLE Concentration: 0.07 ppm (extremely low) Chemical Form: H₂PO₄⁻ (dihydrogen phosphate) and HPO₄²⁻ (hydrogen phosphate) Status: No commercial concentrated seawater phosphorus form exists. The extremely low concentration (0.07 ppm) makes extraction uneconomical compared to phosphate rock mining. Note: Phosphorus recovery from wastewater streams is more promising than seawater extraction.

Production cost analysis

Cost Component$/MT Phosphoric Acid% of Total CostNotes
Phosphate Rock (3.0-3.5 MT needed)$225-35035-45%Varies by rock quality
Sulfuric Acid$150-25020-30%2.5-3.0 MT H₂SO₄ per MT P₂O₅
Energy (Thermal + Electric)$100-15012-18%See detailed breakdown below
Labor$50-806-10%Varies by country
Maintenance & Other$75-12010-15%Equipment, water treatment
Total Production Cost$600-950100%Selling price: $700-1,000/MT

Energy consumption breakdown

Process StageEnergy Consumption% of Total EnergyEnergy TypeKey Operations
Thermal Process (Elemental P)14 MWh/MT P95%ElectricityElectric arc furnace at 1,500°C
Rock Grinding & Beneficiation20-30 kWh/MT rock3%ElectricityCrushing, grinding, flotation
Wet Process Acid Production100-150 kWh/MT P₂O₅15%Steam/ElectricityReaction, filtration, concentration
Phosphogypsum Handling10-20 kWh/MT P₂O₅2%ElectricityPumping, stacking
Wet Process (Phosphoric Acid) Details

Rock Preparation: 5% - Grinding to 60-200 mesh Digestion Reactor: 40% - H₂SO₄ reaction at 70-80°C Filtration: 25% - Gypsum separation Concentration: 25% - Evaporation to 52-54% P₂O₅ Clarification: 5% - Impurity removal

Thermal Process (White Phosphorus) Details

Electric Arc Furnace: 85% - P₄ vapor production Feed Preparation: 5% - Sintering/nodulizing Condensation System: 5% - P₄ recovery Off-Gas Treatment: 3% - CO recovery/burning Material Handling: 2% - Feed systems

Commercial forms & specifications

Product FormChemical FormulaMolecular WeightTypical PurityPrice Range (USD/kg)Main Applications
White PhosphorusP₄123.90 g/mol99.9%$3.50-5.00Chemical intermediates
Red PhosphorusP (polymeric)30.97 g/mol98-99%$2.50-4.00Matches, flame retardants
Phosphoric Acid (85%)H₃PO₄97.99 g/mol85% H₃PO₄$0.70-1.00Fertilizers, food additives
DAP (Diammonium Phosphate)(NH₄)₂HPO₄132.06 g/mol18-46-0$0.55-0.75Fertilizer
MAP (Monoammonium Phosphate)NH₄H₂PO₄115.03 g/mol11-52-0$0.60-0.80Fertilizer, fire retardant
TSP (Triple Superphosphate)Ca(H₂PO₄)₂234.05 g/mol0-46-0$0.45-0.65Fertilizer
Phosphorus PentoxideP₂O₅141.94 g/mol99%+$1.50-2.50Desiccant, chemical synthesis
Phosphorus TrichloridePCl₃137.33 g/mol99%$1.20-1.80Pesticides, plasticizers
Sodium TripolyphosphateNa₅P₃O₁₀367.86 g/mol94-96%$0.80-1.20Detergents, water treatment
Black PhosphorusP (layered)30.97 g/mol99%$500-2000Semiconductors, research
Calcium PhosphateCa₃(PO₄)₂310.18 g/mol96-98%$0.50-1.00Animal feed, toothpaste
GlyphosateC₃H₈NO₅P169.07 g/mol95-98%$3.00-5.00Herbicide

Suppliers by country

🇲🇦 Morocco

CompanyProduct FormsSpecialties
OCP GroupPhosphate rock, phosphoric acid, DAP, MAP, TSP, NPK fertilizersWorld's largest phosphate exporter, integrated mining to fertilizer

🇺🇸 United States

CompanyProduct FormsSpecialties
The Mosaic CompanyPhosphate rock, phosphoric acid, DAP, MAP, MicroEssentialsConcentrated phosphate production in Florida, premium fertilizers
Nutrien Ltd.MAP, DAP, phosphoric acid, specialty phosphatesIntegrated nutrient solutions, retail distribution network

🇷🇺 Russia

CompanyProduct FormsSpecialties
PhosAgroApatite concentrate, phosphoric acid, DAP, MAP, NPK, feed phosphatesHigh-grade apatite from Khibiny deposit, vertically integrated
EuroChemMAP, DAP, NPK fertilizers, phosphoric acidIntegrated production, developing Kovdorsky GOK project

🇸🇦 Saudi Arabia

CompanyProduct FormsSpecialties
Ma'adenPhosphate rock, DAP, MAP, phosphoric acidIntegrated phosphate complex at Wa'ad Al Shamal

🇨🇳 China

CompanyProduct FormsSpecialties
Yuntianhua GroupPhosphate rock, phosphoric acid, DAP, MAP, compound fertilizersLargest phosphate producer in Asia
Guizhou PhosphatePhosphate rock, yellow phosphorus, phosphoric acidMajor thermal phosphorus producer
Wengfu GroupDAP, MAP, NPK, phosphoric acidHigh-efficiency fertilizers

🇯🇴 Jordan

CompanyProduct FormsSpecialties
Jordan Phosphate Mines Company (JPMC)Phosphate rock, DAP, phosphoric acidState-owned integrated producer

🇮🇱 Israel

CompanyProduct FormsSpecialties
Israel Chemicals Ltd. (ICL)Phosphate rock, phosphoric acid, specialty phosphates, MAPFood-grade phosphates, specialty agriculture

🇹🇳 Tunisia

CompanyProduct FormsSpecialties
Compagnie des Phosphates de Gafsa (CPG)Phosphate rock, phosphoric acid, TSP, DAPMajor North African exporter

Market demand by product form

Product FormGlobal Market SizeAsia ShareAmericas ShareGrowth Rate (CAGR)
DAP (Diammonium Phosphate)$25 billion65% share15% share5.5%
MAP (Monoammonium Phosphate)$18 billion55% share25% share5.2%
TSP/SSP (Superphosphates)$12 billion45% share20% share3.8%
NPK Compounds$35 billion50% share20% share6.1%
Phosphoric Acid (Industrial)$8 billion40% share30% share4.5%
Feed Phosphates$3.5 billion45% share25% share4.8%
Food Grade Phosphates$2.8 billion35% share35% share5.0%
Electronic Grade Phosphorus$1.2 billion70% share15% share12.5%

Moles per kilogram

Product FormFormulaMW (g/mol)Moles/kg
White PhosphorusP₄123.908.07
Elemental PhosphorusP30.9732.29
Phosphoric AcidH₃PO₄97.9910.21
Diammonium Phosphate(NH₄)₂HPO₄132.067.57
Monoammonium PhosphateNH₄H₂PO₄115.038.69
Triple SuperphosphateCa(H₂PO₄)₂234.054.27
Phosphorus PentoxideP₂O₅141.947.05

References

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