19 K 39.098

Potassium

alkali metal · Group 1 · Period 4

Atomic properties

Atomic number
19
Z
Atomic weight
39.098[1]
g/mol
Density
0.862 g/cm³
at STP
Melting point
63.38 °C
at 1 atm
Boiling point
759 °C
at 1 atm
Crystal structure
BCC
Electron config.
[Ar] 4s¹
Oxidation states
+1
most common

Market data

No tradeable futures market for K on Yahoo / Stooq. Live market data is not available; pricing in this page is based on contract reference figures from the source documents.

Raw material sources & pricing

Raw Material FormGrade/QualityPrice Paid by RefinersMajor SourcesNotes
Sylvite (KCl)95-98% KCl$300-370/MTCanada, Russia, BelarusPrimary ore, easiest to process
CarnalliteKMgCl₃·6H₂O$250-320/MTGermany, Israel, SpainRequires separation from magnesium
LangbeiniteK₂Mg₂(SO₄)₃$380-450/MTUSA (New Mexico), GermanySulfate form, chloride-free
PolyhaliteK₂Ca₂Mg(SO₄)₄·2H₂O$280-350/MTUK, USA, RussiaComplex processing required
Potash Ore - Primary Raw Material

Current Market Price: $300-370/MT FOB (potassium chloride/MOP) Major Global Reserves: Canada: 1.1 billion MT (23% of world reserves) - Prairie Evaporite Formation Russia: 650 million MT - Verkhnekamskoye deposit Belarus: 750 million MT - Starobin deposit Germany: 150 million MT - Zielitz and Werra deposits 2024 Production Leaders: Canada: 15 million MT (31% of global production) Russia: 6.7 million MT Belarus: 7.5 million MT China: 6 million MT Raw Material Form Grade/Quality Price Paid by Refiners Major Sources Notes Sylvite (KCl) 95-98% KCl $300-370/MT Canada, Russia, Belarus Primary ore, easiest to process Carnallite KMgCl₃·6H₂O $250-320/MT Germany, Israel, Spain Requires separation from magnesium Langbeinite K₂Mg₂(SO₄)₃ $380-450/MT USA (New Mexico), Germany Sulfate form, chloride-free

⚠️ Seawater Potassium Extraction

Commercial Viability: TECHNICALLY POSSIBLE BUT NOT ECONOMICAL Concentration: 380-400 ppm (much higher than aluminum) Chemical Form: K⁺ ions (fully dissociated) Status: While potassium is relatively abundant in seawater (150,000x more concentrated than aluminum), direct extraction is not commercially viable due to the high energy costs of concentrating and separating it from other ions, particularly sodium which is 27x more abundant. Some extraction occurs as a byproduct of sea salt production in bitterns. Note: Potassium is recovered commercially from natural brines (Dead Sea, Great Salt Lake) where concentrations are 10-50x higher than seawater.

Production cost analysis

Cost Component$/MT KCl% of Total CostNotes
Mining & Extraction$80-12035-40%Underground or solution mining
Processing & Refining$50-8020-25%Flotation, crystallization
Energy$30-5012-15%Much lower than metal production
Labor$25-4010-12%Varies by country
Transportation & Logistics$35-6015-18%Bulk shipping costs
Total Production Cost$220-350100%Compare to selling price: $300-370/MT

Energy consumption breakdown

Process StageEnergy Consumption% of Total EnergyEnergy TypeKey Operations
Mining1.5-2.5 MJ/kg40-50%Electricity/DieselDrilling, blasting, hauling
Crushing & Milling0.5-1.0 MJ/kg15-20%ElectricitySize reduction to -10mm
Flotation/Separation0.8-1.2 MJ/kg20-25%ElectricityFroth flotation, magnetic separation
Drying & Compaction0.3-0.5 MJ/kg10-15%Natural GasMoisture removal, granulation
Potassium Metal Production (Sodium Reduction)

KCl + Na → K + NaCl at 850°C Distillation Energy: 15-20 MJ/kg K Sodium Production: 10-12 MJ/kg K equivalent Purification: 3-5 MJ/kg K Total: 30-40 MJ/kg K metal

Alternative: Electrolysis of KOH

Electrolysis: 25-30 MJ/kg K KOH Production: 8-10 MJ/kg K equivalent Mercury concerns: Historical method Modern: Sodium reduction preferred Limited commercial use

Commercial forms & specifications

Product FormChemical FormulaMolecular WeightTypical PurityPrice Range (USD/kg)Main Applications
Potassium Chloride (MOP)KCl74.55 g/mol95-99%$0.30-0.37Fertilizers, chemicals, food
Potassium Sulfate (SOP)K₂SO₄174.26 g/mol98-99%$0.55-0.75Chloride-free fertilizers
Potassium NitrateKNO₃101.10 g/mol98-99.5%$0.65-0.95Fertilizers, pyrotechnics
Potassium HydroxideKOH56.11 g/mol85-95%$0.80-1.20Soaps, batteries, chemicals
Potassium CarbonateK₂CO₃138.21 g/mol98-99%$0.70-1.10Glass, soap, food additive
Potassium MetalK39.10 g/mol98-99.5%$100-250NaK alloys, organic synthesis
Potassium PhosphateK₃PO₄212.27 g/mol98%$1.20-1.80Food, fertilizers, buffers
Potassium PermanganateKMnO₄158.03 g/mol99%$2.50-4.00Water treatment, medical
Potassium FormateCHKO₂84.12 g/mol97-99%$1.50-2.90Drilling fluids, de-icing
Potassium BicarbonateKHCO₃100.12 g/mol99%$0.60-0.90Food, fire suppression
Potassium IodideKI166.00 g/mol99%$35-60Medicine, photography
Potassium BromideKBr119.00 g/mol99%$3.00-5.00Photography, medicine

Suppliers by country

🇨🇦 Canada

CompanyProduct FormsSpecialties
Nutrien Ltd.MOP (standard, granular), SOP, specialty fertilizersWorld's largest potash producer, 20MT capacity
Mosaic CompanyMOP (white, red), specialty gradesPremium potash products, 9MT capacity
K+S Potash CanadaMOP (granular), industrial gradesBethune mine, 2MT capacity

🇷🇺 Russia

CompanyProduct FormsSpecialties
UralkaliMOP (standard, granular, fine), technical grades11.5MT capacity, low production costs
EuroChemMOP, compound fertilizersIntegrated producer, 2.3MT capacity

🇧🇾 Belarus

CompanyProduct FormsSpecialties
BelaruskaliMOP (all grades), technical KClWorld's second-largest producer, 12MT capacity

🇩🇪 Germany

CompanyProduct FormsSpecialties
K+S AGMOP, SOP, specialty fertilizers, industrial saltsEurope's largest producer, sulfate specialties

🇮🇱 Israel / 🇯🇴 Jordan

CompanyProduct FormsSpecialties
Israel Chemicals Ltd (ICL)MOP, SOP, specialty fertilizersDead Sea extraction, 5MT capacity
Arab Potash CompanyMOP (standard, granular, fine)Dead Sea extraction, 2.5MT capacity

🇨🇳 China

CompanyProduct FormsSpecialties
Qinghai Salt Lake IndustryMOP, industrial KCl, lithium co-productionQarhan Salt Lake, 5MT capacity
Zangge MiningMOP, brine-based productionLargest Chinese producer, 2MT capacity

🇺🇸 United States

CompanyProduct FormsSpecialties
Intrepid PotashMOP, SOP, langbeinite (Trio®)Solar evaporation, specialty products
Compass MineralsSOP, specialty fertilizersGreat Salt Lake production

🇨🇱 Chile

CompanyProduct FormsSpecialties
SQM (Sociedad Química y Minera)MOP, KNO₃, specialty fertilizersNitrate co-production, lithium leader

Market demand by product form

Product FormGlobal Market SizeMajor ConsumersMarket ShareGrowth Rate (CAGR)
Muriate of Potash (MOP)$14.5 billionChina, Brazil, USA, India88% of K market3.9%
Sulfate of Potash (SOP)$1.8 billionChina, USA, Europe7% of K market4.5%
Potassium Nitrate$0.9 billionChina, India, USA3% of K market3.2%
Other K Compounds$0.8 billionGlobal industrial2% of K market2.8%
Potassium Metal$45 millionUSA, Europe, Japan1.5%
Potassium Formate$1.15 billionOil & gas industrySpecialty chemical4.7%

Moles per kilogram

Product FormFormulaMW (g/mol)Moles/kg
Potassium MetalK39.1025.58
Potassium ChlorideKCl74.5513.42
Potassium SulfateK₂SO₄174.265.74
Potassium NitrateKNO₃101.109.89
Potassium HydroxideKOH56.1117.82
Potassium CarbonateK₂CO₃138.217.24

References

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